My main research interests focus on understanding the geochemical behavior of radionuclides and co-contaminants produced either at the front or back end of the nuclear fuel cycle in surface and subsurface environments. Until present, I have worked in projects that covered:
- mechanistic understanding of the interactions between anthropogenic complexing agents (EDTA, NTA, ISA, picolinic acid) and radionuclides (Tc, U, Th, Sr, Cs) and their effect on mobility in different solid phase systems (natural sand, silty loam soil).
- development of an ion exchange model to obtain a thermodynamic database describing the sorption of trace elements (U and Ra) on clays (kaolinite) in the presence of major ions.
- determination of rates and mechanisms of uranyl oxyhydroxide and phosphate minerals dissolution under a flow-through porewater regime, and study the effect of dissolved carbonate concentration on dissolution.
- characterisation of nuclear fuel particles from contaminated soils and sediments of Chernobyl's and Fukushima's exclusion zones.
In order to produce successful research with high quality understanding, and due to my analytical chemistry background, my research always features a wide range of analytical, radioanalytical and spectroscopic techniques, and when necessary I have developed and optimized the methodology. Among these techniques, I am proficient with ICP-MS, ICP-OES, IC, TOC, UV-Vis spectrometry, gamma spectrometry, as well as solid phase characterization techniques such particle size, BET surface area, autoradiography, scanning electron microscopy (SEM), micro X-ray fluorescence (µXRF), X-ray diffraction (XRD), and X-ray absorption spectroscopy (XAS) at synchrotron light source facilities. Moreover, I use chemical, geochemical and reactive transport calculations and modelling (HYDRA/Medusa, Visual MINTEQ, PHREEQC, CrunchFlow) to support experimental work and gain further mechanistical understanding.
Recently, I have also been involved in the method development and analyses of plasma's seleno proteins and aminoacids by HPLC--ICP-MS to study the effect of different dietary selenium sources on the growth and health of fast-growing pigs in the Norwegian porcine industry.
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Publikasjoner
Full research papers (published)
13. Kaspharov V.*, Salbu B., Simonucci C., Levchuk S., Reinoso-Maset E., Lind O.C., Maloshtan I., Protsak V., Courbet C., Nguyen H. (2020) “Validation of a fuel particle dissolution model with samples from the Red Forest within the Chernobyl exclusion zone", Journal of Environmental Radioactivity, 223-224, 106387
https://doi.org/10.1016/j.jenvrad.2020.10638712. Reinoso-Maset E.*, Perdrial N., Steefel C.I., Um W., Chorover J., O’Day P.A. (2020) “Dissolved carbonate and pH control the dissolution of uranyl phosphate minerals under flow conditions", Environmental Science and Technology, 50, 10, 6031-6042
https://doi.org/10.1021/acs.est.9b0644811. Falk M.*, Bernhoft A., Reinoso-Maset E., Salbu B., Lebed P.J., Framstad T., Fuhrmann H., Oropeza-Moe M. (2020) “Beneficial antioxidant status of piglets from sows fed organic selenium", Journal of Trace Elements in Medicine and Biology, 58, 126439
https://doi.org/10.1016/j.jtemb.2019.12643910. Reinoso-Maset E.*, Brown J., Pettersen M.N., Steenhuisen F., Tetteh A., Wada T., Hinton T.G., Salbu B., Lind O.C. (2020) “Linking heterogenous distribution of radiocaesium in soils and pond sediments in the Fukushima Daiichi exclusion zone to mobility and potential bioavailability", Journal of Environmental Radioactivity, 211, 106080
https://doi.org/10.1016/j.jenvrad.2019.1060809. Wærsted F.M.*, Jensen K.A., Reinoso-Maset E., Skipperud L. (2018) “High throughput, direct determination of 226Ra in water and digested geological samples”, Analytical Chemistry, 90(20), 12246-12252
https://doi.org/10.1021/acs.analchem.8b034948. Wang G., Um W.*, Wang Z., Reinoso-Maset E., Washton N., Mueller K.T., Perdrial N., O'Day P.A., Chorover J. (2017) “Uranium release from acidic weathered Hanford sediments: single-pass flow-through and column experiments”, Environmental Science & Technology, 51(19), 11011-11019
https://doi.org/10.1021/acs.est.7b034757. Reinoso-Maset E.*, Steefel C.I., Um W., Chorover J., O’Day P.A. (2017) “Rates and mechanisms of uranyl oxyhydroxide mineral dissolution”, Geochimica et Cosmochimica Acta, 207, 298-321
https://doi.org/10.1016/j.gca.2017.03.0096. Reinoso-Maset E.*, Ly J. (2016) “Study of trace level uranium(VI) and radium(II) sorption on kaolinite using a multisite ion exchange model”, Journal of Environmental Radioactivity, 157, 136-148
https://doi.org/10.1016/j.jenvrad.2016.03.0145. Reinoso-Maset E.*, Ly J. (2014) “Study of major ions sorption equilibria to characterize the ion exchange properties of kaolinite”, Journal of Chemical and Engineering Data, 59(12), 4000-4009
https://doi.org/10.1021/je50054384. Reinoso-Maset E.*, Worsfold P.J., Keith-Roach M.J. (2013) “Effect of organic complexing agents on the interactions of U(VI), Sr(II) and Cs(I) with natural sand”, Chemosphere, 91(7), 948-954
https://doi.org/10.1016/j.chemosphere.2013.01.1053. Reinoso-Maset E.*, Worsfold P.J., Keith-Roach M.J. (2012) “Evaluation of electrospray ionisation mass spectrometry as a technique for the investigation of competitive interactions: A case study of the ternary Th-Mn-EDTA system”, Rapid Communications in Mass Spectrometry, 26(23), 2755–2762
https://doi.org/10.1002/rcm.64042. Reinoso-Maset E.*, Worsfold P.J., Keith-Roach M.J. (2012) “The effect of EDTA, NTA and picolinic acid on Th(IV) mobility in a ternary system with natural sand”, Environmental Pollution, 162, 399–405
https://doi.org/10.1016/j.envpol.2011.11.0381. Reinoso Maset E., Handley S., Fisher A., Heydon A., Worsfold P.J., Cartwright A.J., Keith-Roach M.J.* (2006), “The effect of organic co-contaminants on technetium and rhenium speciation and solubility under reducing conditions”, Environmental Science & Technology, 40(17), 5472-5477
https://doi.org/10.1021/es061157fConference papers
3. Reinoso-Maset E.*, Hainos D., Ly J. (2012) “Sorption of uranium(VI) and radium(II) at trace level onto kaolinite and montmorillonite”, Mineralogical Magazine, 76(6), 2275.
https://goldschmidtabstracts.info/2012/2275.pdf2. Keith-Roach M.J.*, Reinoso-Maset E., May C.C., Young L., Worsfold P.J., (2011) “The influence of co-contaminant complexing agents on radionuclide environmental behaviour”, Mineralogical Magazine, 75(3), 1165.
https://goldschmidtabstracts.info/2011/1165.pdf1. Reinoso-Maset E.*, Worsfold P.J., Keith-Roach M.J. (2008) “Radionuclides, organic complexing agents and solid phases: Exploring their interactions”, Geochimica et Cosmochimica Acta, 72 (12 Suplement), 785.
https://goldschmidtabstracts.info/2008/785.pdfPh.D. research thesis
Reinoso-Maset, Estela (2010) "Aqueous and solid phase interactions of radionuclides with organic complexing agents", Faculty of Science and Technology, University of Plymouth, UK
https://pearl.plymouth.ac.uk/handle/10026.1/300 -
Forskning & prosjekt
Forskningsområder
Tema:
- Miljø
Spesialområder:
- Radiokjemi
Forskningsområder:
- Kjemi
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Annet & CV
04/2017 – present
Research scientist; Centre for Environmental Radioactivity, Norwegian University of Life Sciences (NMBU), Aas, Norway04/2013 – 12/2015
Postdoctoral researcher; University of California Merced, USA01/2011 – 01/2013
Postdoctoral researcher; Commissariat à l’énergie atomique et aux énergies alternatives (CEA), Centre de Saclay, France10/2007 – 12/2010
Laboratory teaching demonstrator and marker; University of Plymouth, UK09/2006 – 11/2010
Ph.D. in Environmental Radiochemistry; University of Plymouth, UK01/2005 – 07/2005
Erasmus post-graduate exchange student; University of Plymouth, UK, and Universidade de Vigo, Spain09/1998 – 06/2004
Licenciatura en Ciencias Químicas (Química Fundamental – Química Analítica); Universidade de Vigo, Spain